soil

Ohio VAP Soil Standards - Volatile Organic Compounds (VOCs)

Current Ohio VAP generic direct-contact soil cleanup levels for VOCs including benzene, TCE, PCE, vinyl chloride, and BTEX. Cited to OAC 3745-300.

Verified March 22, 2026 Source: Ohio Administrative Code 3745-300-08

Overview

Ohio’s Voluntary Action Program (VAP) establishes generic direct-contact soil standards under OAC 3745-300-08. These are the numbers that consultants compare Phase II soil analytical results against to determine if a site meets cleanup requirements.

The standards below are from the current CIDARS database (February 2025 version, accompanying the VAP rules effective February 16, 2025). They represent the single-chemical generic direct-contact soil standard (GDCSS) - the lowest applicable value across all exposure pathways for each land use category.

Important distinction: These are direct-contact standards only. Soil can fail on other pathways even if direct-contact standards are met - particularly the soil-to-indoor-air pathway (vapor intrusion) and the soil leaching-to-groundwater pathway. A complete VAP evaluation requires screening against all applicable pathway standards, not just direct contact.

How the Standards Are Determined

The VAP generic soil standards are the lowest value from multiple exposure pathways evaluated for each chemical, land use, and receptor combination. For residential standards, this typically includes non-cancer risk, cancer risk, and soil saturation limits. The single-chemical GDCSS reported in CIDARS is the most restrictive value across all of these.

For VOCs, the residential soil standard is often driven by the vapor intrusion pathway (soil-to-indoor-air), which produces much lower values than the direct-contact ingestion/dermal pathway alone. This is why some VOC soil standards seem surprisingly low compared to what you might expect based on toxicity alone.

Residential Direct-Contact Soil Standards

These apply to properties with residential land use, including single-family homes, apartments, schools, and daycares.

Showing 101 of 101 chemicals
Chemical CAS Number Residential (mg/kg) Commercial/Industrial (mg/kg)
Acetaldehyde 75-07-0 210 860
Acetone 67-64-1 110,000 110,000
Acetonitrile 75-05-8 2,000 8,600
Acrolein 107-02-8 0.3605 1.52018157
Acrylic Acid 79-10-7 50 210
Acrylonitrile 107-13-1 6.0867 30
Allyl Alcohol 107-18-6 140 19,000
Allyl Chloride 107-05-1 4.1 17
Benzene 71-43-2 28 130
Benzotrichloride 98-07-7 1.0696 10.063
Benzyl Chloride 100-44-7 25 130
Bis(2-chloro-1-methylethyl) Ether 108-60-1 1,000 1,000
Bromodichloromethane 75-27-4 7.3 33
Bromoform 75-25-2 460 910
Bromomethane 74-83-9 17 76
Butadiene, 1,3- 106-99-0 1.8714 8.5
Butanol, N- 71-36-3 7,600 7,600
Butylbenzene, n- 104-51-8 110 110
Carbon Disulfide 75-15-0 740 740
Carbon Tetrachloride 56-23-5 16 74
Carbonyl Sulfide 463-58-1 170 710
Chlorobenzene 108-90-7 660 760
Chloro-1,3-butadiene, 2- 126-99-8 0.2534 1.10685666
Chloroform 67-66-3 7.9156 35
Chloromethane 74-87-3 280 1,200
Chloromethyl Methyl Ether 107-30-2 0.4976 2.3
Crotonaldehyde, trans- 123-73-9 7.3 69
Cumene 98-82-8 270 270
Cyclohexane 110-82-7 120 120
Cyclohexanone 108-94-1 5,100 5,100
Dibromo-3-chloropropane, 1,2- 96-12-8 0.1311 1.62585265
Dibromochloromethane 124-48-1 170 800
Dibromoethane, 1,2- 106-93-4 0.8864 4.2
Dichloro-2-butene, 1,4- 764-41-0 0.0539 0.235
Dichlorodifluoromethane 75-71-8 850 850
Dichloroethane, 1,1- 75-34-3 89 390
Dichloroethane, 1,2- 107-06-2 11 52
Dichloroethylene, 1,1- 75-35-4 19 1,200
Dichloroethylene, 1,2-cis- 156-59-2 310 2,400
Dichloroethylene, 1,2-trans- 156-60-5 1,900 1,900
Dichloropropane, 1,2- 78-87-5 39 170
Dichloropropane, 1,3- 142-28-9 1,500 1,500
Dichloropropene, 1,3- 542-75-6 43 230
Dihydrosafrole 94-58-6 210 1,500
Dimethylaniline, N,N- 121-69-7 310 830
Dimethylformamide 68-12-2 6,100 39,000
Dimethylhydrazine, 1,2- 540-73-8 0.0188 0.137
Dioxane, 1,4- 123-91-1 110 850
Epoxybutane, 1,2- 106-88-7 400 1,700
Ethoxyethanol, 2- 110-80-5 6,000 39,000
Ethyl Acetate 141-78-6 1,600 6,600
Ethyl Acrylate 140-88-5 110 540
Ethyl Chloride (Chloroethane) 75-00-3 2,100 2,100
Ethyl Ether 60-29-7 10,000 10,000
Ethyl Methacrylate 97-63-2 1,100 1,100
Ethylbenzene 100-41-4 140 480
Ethylene Diamine 107-15-3 14,000 190,000
Ethylene Oxide 75-21-8 0.0514 0.624
Ethyleneimine 151-56-4 0.0627 0.325
Formaldehyde 50-00-0 260 1,400
Formic Acid 64-18-6 340 110,000
Glycidaldehyde 765-34-4 49 620
Hexane, N- 110-54-3 140 140
Hydrazine 302-01-2 0.7794 3.7
Isobutyl Alcohol 78-83-1 10,000 10,000
Methacrylonitrile 126-98-7 15 390
Methanol 67-56-1 110,000 110,000
Methyl Ethyl Ketone (2-Butanone) 78-93-3 28,000 28,000
Methyl Hydrazine 60-34-4 160 4,700
Methyl Isobutyl Ketone (4-methyl-2-pentanone) 108-10-1 3,400 3,400
Methyl Isocyanate 624-83-9 12 49
Methyl Methacrylate 80-62-6 2,400 2,400
Methyl tert-Butyl Ether (MTBE) 1634-04-4 1,100 5,400
Methylene Chloride 75-09-2 740 3,300
Naphthalene 91-20-3 45 230
Nickel Carbonyl 13463-39-3 1,600 36,000
Phosgene 75-44-5 0.7711 3.2
Propargyl Alcohol 107-19-7 310 9,300
Propionaldehyde 123-38-6 190 790
Propylene Oxide 75-56-9 45 330
Styrene 100-42-5 870 870
Tetrachlorobenzene, 1,2,4,5- 95-94-3 4.7 140
Tetrachloroethane, 1,1,1,2- 630-20-6 49 230
Tetrachloroethane, 1,1,2,2- 79-34-5 15 71
Tetrachloroethylene 127-18-4 170 170
Toluene 108-88-3 820 820
Trichloroethane, 1,1,1- 71-55-6 640 640
Trichloroethane, 1,1,2- 79-00-5 28 130
Trichloroethylene 79-01-6 10.0803 48
Trichlorofluoromethane 75-69-4 1,200 1,200
Triethylamine 121-44-8 290 1,200
Vinyl Acetate 108-05-4 2,300 2,700
Vinyl Bromide 593-60-2 6.4 28
Vinyl Chloride 75-01-4 1.2815 49
Xylenes 1330-20-7 260 260
Butylbenzene, sec- 135-98-8 140 140
Butylbenzene, tert- 98-06-6 180 180
Chloroacetaldehyde, 2- 107-20-0 40 260
Dibromomethane (Methylene Bromide) 74-95-3 59 250
Dimethylhydrazine, 1,1- 57-14-7 0.1435 0.608
Propyl benzene 103-65-1 260 260

† Listed in CIDARS under Supplemental Criteria rather than as an Appendix A generic numerical standard.

Commercial/Industrial Direct-Contact Soil Standards

These apply to properties with commercial or industrial land use where workers are the primary receptors.

ContaminantCAS NumberC/I GDCSS (mg/kg)Construction Worker (mg/kg)
Benzene71-43-21301,100
Toluene108-88-3820820
Ethylbenzene100-41-4480480
Xylenes (total)1330-20-7260260
Naphthalene91-20-3230560
Trichloroethylene (TCE)79-01-64819
Tetrachloroethylene (PCE)127-18-4170170
Vinyl Chloride75-01-449190
1,1-Dichloroethylene75-35-41,20019
cis-1,2-Dichloroethylene156-59-22,4002,400
MTBE1634-04-45,4008,900
1,2,4-Trimethylbenzene95-63-6220220
1,3,5-Trimethylbenzene108-67-8180180

Practical Notes for Consultants

Residential vs. Commercial/Industrial - When It Matters

The gap between residential and C/I standards varies enormously by contaminant. For BTEX compounds (benzene, toluene, ethylbenzene, xylenes), the residential and C/I numbers are within an order of magnitude of each other. But for chlorinated solvents like vinyl chloride, the residential standard (1.3 mg/kg) is almost 40 times lower than the commercial/industrial standard (49 mg/kg). This means land-use classification has a huge impact at chlorinated solvent sites.

If your client is considering a land-use restriction to avoid residential standards, make sure they understand the long-term implications - use restrictions are recorded with the deed and affect property value and future flexibility.

Soil Saturation Limits

Several contaminants in the table above - toluene (820 mg/kg), xylenes (260 mg/kg), PCE (170 mg/kg), and the trimethylbenzenes - have residential standards that are actually driven by the soil saturation concentration, not by a risk calculation. Soil saturation is the maximum concentration a soil can hold before the contaminant exists as a separate phase (NAPL). When you see the residential and C/I standards at the same value, it’s usually because both are capped at soil saturation.

Vapor Intrusion - The Hidden Driver

For most VOCs, the soil-to-indoor-air pathway produces the most restrictive cleanup standard. The GDCSS values in the tables above already account for this, but it’s worth understanding because it affects how you design your sampling program. If you’re only collecting soil samples for direct-contact analysis and not evaluating the vapor intrusion pathway separately, you’re missing the pathway that’s most likely to drive cleanup at a VOC site.

Ohio’s vapor intrusion screening levels are derived from the CIDARS indoor air standards combined with attenuation factors. See our Ohio Vapor Intrusion Screening Levels page for the specific numbers.

VAP vs. BUSTR Soil Standards

If you’re working at a petroleum UST site regulated by BUSTR (OAC 1301:7-9), be aware that BUSTR has its own set of soil action levels that are different from the VAP standards. The BUSTR closure action levels (Table 2.3 of the BUSTR TGM) are specifically designed for petroleum UST closure assessments and assume residential land use, drinking water groundwater, and less than 15 feet to groundwater. They are not interchangeable with VAP standards.

For a comparison, see our Ohio BUSTR Corrective Action Standards page.

PID Screening in the Field

When collecting soil samples for VOC analysis, field screen every sample interval with a PID (photoionization detector). The PID reading helps you identify the most contaminated intervals for laboratory analysis and provides real-time information about VOC distribution. Use a 10.6 eV lamp for BTEX compounds - the 11.7 eV lamp detects more compounds but is less selective.

PID readings are not a substitute for laboratory analysis, but they’re invaluable for directing your sampling program and avoiding the expensive mistake of sending the wrong samples to the lab.

Sample Collection for VOCs

Soil samples for VOC analysis require special handling to prevent volatile losses:

  • Use EnCore samplers or equivalent - these are sealed, zero-headspace containers that preserve VOCs from the moment of collection
  • Alternatively, use brass or stainless steel sleeves sealed with PTFE caps and shipped on ice
  • Collect samples from the freshly exposed face immediately after advancing the boring - don’t let the soil sit exposed to air
  • Do not composite soil samples for VOC analysis - each sample must be a discrete grab from a specific depth
  • Maintain chain of custody and ship on ice to the lab within the method-specified holding time

Comparison with EPA Regional Screening Levels

The Ohio VAP soil standards are generally similar to but not identical to EPA’s Regional Screening Levels (RSLs). Key differences include the exposure factors used (Ohio uses its own parameters in some cases), the toxicity values applied (Ohio follows its own hierarchy), and the specific pathways evaluated. When both a VAP standard and an RSL exist for the same contaminant, use the VAP standard for Ohio VAP sites.

For non-VAP work (federal Superfund, due diligence screening), see our EPA RSL Tables - 2026 Update Explained (coming soon) page.

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Ohio VAP generic direct-contact soil standards for VOCs - residential, commercial/industrial, and construction worker. CIDARS February 2025.

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